个人简介
姓名:刘圣男
学院:化学与材料工程学院
指导老师:向卫东教授
研究方向:LED发光材料
科研感言:
不从泥泞不堪的小道上迈步,就踏不上铺满鲜花的大路
获奖情况:
“温州大学未来管理者”荣誉称号
“温州大学优秀学生干部”荣誉称号
温州大学“研究生学业综合一等奖学金”
研究生“国家奖学金”等荣誉。
论文:
《Sn-doped CsPbBr3 QDs glasses with excellent stability and optical properties for WLED》
(具有优异稳定性和光学性能的掺杂锡的CsPbBr3量子点玻璃白色发光二极管)
发表期刊:Chemical Engineering Journal 361 (2019): 937-944.(第一作者,SCI 期刊1区, IF=8.355)
● 论文摘要
CsPbX3 (X =Cl, Br, I) quantum dots (QDs) are considered to be candidate materials for applications in the field of photoelectric devices due to their remarkable photoelectric properties, such as high photoluminescence quantum yields (PLQYs), narrow emission wavelengths and easy synthesis. However, their instability and high toxicity restrict the further development of QDs. Here, we synthesized Sn-doped CsPb1−xSnxBr3 perovskite nanocrystals in borosilicate glasses (B2O3-SiO2-ZnO, BSZ) by traditional melt-quenching for the first time. The sample exhibited excellent air stability and thermal stability. Based on these results, white-light-emitting devices were fabricated by incorporating CsPb0.64Sn0.36Br3 QDs glasses and commercial red phosphor (CaAlSiN3:Eu2+) into a blue LED device. The tunable color coordinates of (0.3179-0.3596, 0.3174-0.3665) and adjustable correlated color temperature (CCT) from 6119K to 3128K were successfully achieved in the white light area, which could promote the application of metal ion-doped perovskite QDs in photoelectric devices.
● 论文集锦
•Sn-doped CsPbBr3 QDs glasses were successfully synthesized by melt-quenching.
•QDs glasses hold excellent luminescent properties while reducing toxicity.
•The stability of Sn-doped CsPbBr3 QDs glasses were greatly improved.
•WLED based on Sn-doped CsPbBr3 QDs glasses realized tunable CCT, CRI and CIE.
科研成果展示
参与基金项目:
1. « 激光照明显示用高量子产率高热稳定性稀土掺杂CsPb(BrxI1-x)3:Re红光微晶玻璃制备» 国家自然科学基金面上项目 (项目编号51872207)
2. « 新一代白光LED用全光谱CsPbX3(X=Cl、Br、I)钙钛矿量子点微晶玻璃的研究» 国家自然科学基金面上项目 (项目编号:51672192)
发表论文,专利:
1. Liu, Shengnan, et al. "Sn-doped CsPbBr3 QDs glasses with excellent stability and optical properties for WLED." Chemical Engineering Journal 361 (2019): 937-944.(第一作者,SCI 期刊1区, IF=8.355)
2. Liu, Shengnan, et al. Water-stable all-inorganic CsPb1-XSnXBr2I perovskite quantum dots encapsulated in paraffin for white light-emitting diodes. Journal of Alloys and Compounds, 806, (2019),1022-1028.(SCI 期刊2区,IF=4.175)
3. 一种CsPb(1-x)SnXBr3量子点微晶玻璃材料专利(第一作者,温州大学,公开号CN109553303A)
4 Shao G, Liu S, et al. KxCs1-xPbBr3 NCs glasses possessing super optical properties and stability for white light emitting diodes. Chemical Engineering Journal, 2019, 122031. (第二作者,IF= 8.355 SCI一区)
5. He M, Liu S, et al. SiO2- improved stability of Mn-doped CsPbBr0. 5I2.5 NC and their application for white LED. Journal of the American Ceramic Society, 2019, 102, 930-935. (第二作者,IF= 3.094 SCI二区)
6. Liu J, Liu S, et al. Sm3+-doped CsPbBr3 NCs glass: A luminescent material for potential use in lighting engineering. Ceramics International, 2019.(第二作者,IF= 3.45 SCI二区)
7. Ding L, Liu S, et al. Stable Zn-doped CsPbBr3 NCs glasses toward an enhanced optical performance for WLED. Ceramics International, 2019.(第二作者,IF= 3.45 SCI二区)